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强磁场对Bi-Mn合金半固态凝固过程中MnBi析出相组织的影响

Effects of high magnetic field on microstructures of MnBi precipitated phase in Bi-Mn alloy solidified from mushy zone

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【作者】 王晖任忠鸣徐匡迪黄晖王秋良严陆光

【Author】 WANG Hui~1, REN Zhong-ming~2, XU Kuang-di~2, HUANG Hui~1, WANG Qiu-liang~1, YAN Lu-guang~1 (1. Institute of E1ectrical Engineering, Chinese Academy of Sciences, Beijing 100080, China; 2. Department of Materials Science and Engineering, Shanghai University, Shanghai 200072, China)

【机构】 中国科学院电工研究所上海大学材料科学与工程学院中国科学院电工研究所 北京100080上海200072北京100080北京100080

【摘要】 在Bi 6%Mn合金从高于355℃(升温过程中MnBi化合物磁性转变温度)的固液两相区凝固过程中,研究了MnBi析出相组织在无磁场和强磁场条件下的演化过程。结果表明:在无磁场条件下MnBi析出相形态在340℃(MnBi相顺磁铁磁转变温度)附近发生突变,由较规则的六方块状变为沿ab面长大的不规则片状;10T磁场条件下析出相形态突变的温度提高到355℃左右。另外,10T磁场能够控制析出相晶粒以c轴平行磁场取向、定向聚合和熔合长大,使析出相的最终形态又趋向较规则的六方块状。

【Abstract】 The structural evolution of the MnBi precipitated phase in Bi-6%Mn alloy was experimentally studied with or without a high magnetic field applied during the alloy solidified from the semi-solid zone above 355 ℃, the magnetic transition temperature of MnBi compound upon heating. In the absence of a magnetic field, it was found that the precipitated phase changed suddenly from a shape similar to its hexagonal single crystal to an irregular oblate shape formed by a rapid growth of the grains along their ab-planes at the temperature near 340 ℃, the magnetic transition temperature of MnBi compound upon cooling. In the present of a 10 T magnetic field, the temperature at which the shape changed abruptly was increased to 355 ℃ or so. Furthermore, the MnBi grains were controlled by the 10 T field to be oriented with their c-axes, directionally aggregated and grown up along the field so that the ultimate shape of the precipitated phase was tend to be regular again.

【基金】 国家自然科学基金资助项目(50234020;50307014)
  • 【文献出处】 中国有色金属学报 ,The Chinese Journal of Nonferrous Metals , 编辑部邮箱 ,2004年07期
  • 【分类号】TG111.4
  • 【被引频次】5
  • 【下载频次】283
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