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种子溶胀聚合法制备新型分子烙印聚合物
Novel Molecularly Imprinted Polymer Prepared by Seed Swelling Polymerization
【摘要】 用超声波乳液聚合法,合成聚苯乙烯微粒,并以之作为种子,经过两步溶胀,以茶碱为模板分子,甲基丙烯酸为功能单体,乙二醇二丙烯酸酯为交联剂,聚合得到粒度均匀的球形分子烙印聚合物。研究了影响分子烙印聚合物形貌和吸附性能的因素,表明该聚合物对模板化合物茶碱具有良好的特异性吸附性能。
【Abstract】 Ultrasonically emulsion polymerization was used to produce polystyrene microparticles. Using polystyrene particles as seed, theophylline as imprinted molecular , methacrylic acid as a functional monomer and ethylene glycol dimethacrylate as cross-linker, uniformly sized molecular imprinted polymers(MIP) were prepared by two step swelling polymerization. The absorption capability was determined and found the MIP has absorption with a good selectivity on theophylline. The factors which effect on the size and shape of the MIP were also discussed.
【关键词】 分子烙印聚合物;
种子溶胀;
超声波乳液聚合;
茶碱;
【Key words】 molecularly imprinted polymer; seed swelling; ultrasonically emulsion polymerization; theophylline;
【Key words】 molecularly imprinted polymer; seed swelling; ultrasonically emulsion polymerization; theophylline;
【基金】 国家自然科学基金资助项目(20202015);国家教育部博士点基金资助项目(20020558026)
- 【文献出处】 中山大学学报(自然科学版) ,Acta Scientiarum Naturalium Universitatis Sunyatseni , 编辑部邮箱 ,2004年03期
- 【分类号】O631
- 【被引频次】31
- 【下载频次】381