【摘要】 理论研究了碳环对称转子的碳环面积与反磁化率的关系 ;讨论了对称转子振动谱带的转子结构 ,表明转子能级恰好处于微波范围 .同时基于量子力学中二维势阱理论和量子化学的离域效应 ,揭示出碳环面积越大 ,则系统能量越低 ,转动常数B和能级间隔会不断减少 ,从而有利于吸收低频微波 .量子力学方法B3P86 /6 311G计算完全证实了理论分析 .根据理论指导 ,研究了新型碳团簇材料AⅡ在低频段 2 .0GHz5 .0GHz范围内的微波透射性能 ,讨论了碳化温度、厚度、分子材料Ⅱ对其微波透射性能的影响 .更多还原

【Abstract】 The relation between antimagnetic susceptibility and the area of C-ring symmetric rotators has been calculated.The bigger area of symmetric rotators will cause the rotational energy structure of vibrational spectrabeing to locate in the range of microwave spectra.At the same time,based on the theory of the planar potential well in quantum mechanics and the effect of the delocalization in quantum chemistry,the present work discovers that the bigger the area of C-rings, the lower the energy level interval,and then the rotational constants B will decrease continuously,which make C-rings be propitious to absorb microwave of low frequency bands.The calculated results of quantum mechanics B3P86/6-311G authenticate entirely the theoretic analysis.Moreover,based on the theoretic instruction,the present work has studied the microwave transmissivity of carbon cluster-like absorbing materials AⅡ.The influences of different carbonized temperatures,thickness and material Ⅱ on the transmissivity are reviewed.更多还原