【摘要】 以纯度为84.21%的工业菲为原料,冰醋酸作溶剂,卤素化合物作为氧化剂氧化菲合成菲醌的氧化体系,菲醌最高收率可达63.23%,并确定了影响此反应的主要因素和最佳反应条件.该工艺反应条件温和,操作简单,无"三废"污染问题,溶剂可循环利用.更多还原

【Abstract】 In the paper,phenanthrenequinone was prepared by oxidation of phenanthrene((84.21%)) with halogen compound in the presence of glacial acetic acid.The yield of phenanthrenequinone can reach 63.23%.Chief influential factors and optimum processing condition of this reaction were discussed.The reaction condition is moderate;the technological process is comparatively simple;the environment is not polluted,and the solvent can be recycled.更多还原