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Studies on Spinel LiMn2O4 Cathode Material Synthesized from Different Mn Sources

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【作者】 唐致远冯季军彭亚宁

【Author】 TANG Zhiyuan FENG Jijun and PENG Yaning School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China School of Chemistry and Chemical Engineering, Jinan University, Jinan 250022, China

【机构】 School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072ChinaSchool of Chemistry and Chemical EngineeringJinan UniversityJinan 250022China

【摘要】 <正> The spinel LiMn2O4 cathode material was synthesized with the solid-state reaction method. Four manganese compounds including electrolytic manganese dioxide (EMD), MnCO3, Mn3O4 and nano-EMD were used as Mn sources while LiOH·H2O was used as the uniform Li source. The crystal structure characteristics of these samples produced were investigated by means of XRD, SEM, particle size distribution analysis and specific surface area testing. Their electrochemical properties were also studied by comparing their specific capacity, charge and discharge efficiency and cycle performance.

【Abstract】 The spinel LiMn2O4 cathode material was synthesized with the solid-state reaction method. Four manganese compounds including electrolytic manganese dioxide (EMD), MnCO3, Mn3O4 and nano-EMD were used as Mn sources while LiOH·H2O was used as the uniform Li source. The crystal structure characteristics of these samples produced were investigated by means of XRD, SEM, particle size distribution analysis and specific surface area testing. Their electrochemical properties were also studied by comparing their specific capacity, charge and discharge efficiency and cycle performance.

【基金】 Supported by the National Natural Science Foundation of China (No. 20273047).
  • 【文献出处】 Chinese Journal of Chemical Engineering ,中国化学工程学报(英文版) , 编辑部邮箱 ,2004年01期
  • 【分类号】O614
  • 【被引频次】6
  • 【下载频次】56
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