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外加电位对X70管线钢在近中性pH溶液中的应力腐蚀破裂的影响

EFFECT OF APPLIED POTENTIALS ON STRESS CORROSION CRACKING OF X70 PIPELINE STEEL IN NEAR-NEUTRAL-pH SOLUTIONS

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【作者】 郭浩李光福蔡珣周建江黄春波杨武

【Author】 GUO Hao 1,2,LI Guangfu2,CAI Xun1,ZHOU Jianjiang2,HUANG Chunbo2,YANG Wu2 (1.Materials College of Shanghai Jiaotong University,Shanghai 200030; 2 Shanghai Research Institute of Materials,Shanghai 200437)

【机构】 上海交通大学材料学院上海材料研究所上海材料研究所 上海200030上海材料研究所上海200437上海200437上海200030上海200437

【摘要】 采用慢应变速率试验 (SSRT)研究了不同电位下X70管线钢在近中性pH溶液中的应力腐蚀破裂 (SCC)行为 ,同时研究了溶液中通入不同含量CO2 对SCC的影响 .结果表明 ,X70管线钢在近中性pH溶液中的开裂方式是穿晶型的 ,具有准解理特征 ,并且随着外加阴极电位的降低 ,SCC敏感性增加 ;随CO2 含量的增加 ,pH值降低 ,SCC敏感性增加 .均表现为氢致开裂占主导 .

【Abstract】 The stress corrosion cracking(SCC)behavior of X70 pipeline steel in near-neutral-pH solutions at different applied potentials and the effect of different levels of CO 2 on SCC were studied with slow strain rate testing(SSRT).The results showed that the cracking mode of X70 pipeline steel in near-neutral-pH solutions was transgranular,with the features of quasi-cleavage.The susceptibility to SCC increased as the applied potential moved towards the cathodic direction.The value of pH decreased with the increased addition of CO 2 in the solution,which increased the susceptibility to SCC.Hydrogen induced cracking(HIC)dominated the process.

【基金】 国家重点基金研究专项目经费资助项目 (G19990 65 0 );上海市科技发展基金项目 ( 0 2 5 2 5 80 3 6);上海市自然科学基金 ( 0 2ZE14 0 3 1)
  • 【文献出处】 中国腐蚀与防护学报 ,Journal of Chinese Society For Corrosion and Protection , 编辑部邮箱 ,2004年04期
  • 【分类号】TG172.8
  • 【被引频次】32
  • 【下载频次】341
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