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阻抑动力学光度法测定食物中痕量草酸

Determination of Trace Oxalic Acid in Natural Foodstuffs by Inhibition Kinetic Spectrophotometry

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【作者】 刘连伟孙衍华王秀峰

【Author】 LIU Lian-Wei a*, SUN Yan-Huaa, WANG Xiu-Fengb (aCollege of Chemistry and Material Science;bCollege of Horticulture, Shandong Agricultural University,Taian 271018)

【机构】 山东农业大学化学与材料科学学院山东农业大学园艺学院 泰安271018泰安271018泰安271018

【Abstract】 It is well known that hydrogen peroxide in dilute H 2SO 4 solution discolorizes bromocresol purple, while oxalic acid can sensitively inhibit the discoloration reaction or slow the reaction rate. The kinetic beha- vior of the inhibition reaction has been investigated and a kinetic spectrometric method for determination of trace oxalic acid was developed with detection limit 2.8×10 -8 g/mL and the linear range of the determination was 0~8×10 -7 g/mL oxalic acid. ε 430=1.50×10 5 L/(mol·cm). The method has been satisfactorily applied to the determination of trace oxalic acid in fruits, greens and cereals.

【基金】 国家科技攻关计划课题资助项目 (2 0 0 1BA5 0 3B0 4)
  • 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2004年03期
  • 【分类号】TS207
  • 【被引频次】6
  • 【下载频次】98
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