节点文献
阻抑动力学光度法测定食物中痕量草酸
Determination of Trace Oxalic Acid in Natural Foodstuffs by Inhibition Kinetic Spectrophotometry
【Abstract】 It is well known that hydrogen peroxide in dilute H 2SO 4 solution discolorizes bromocresol purple, while oxalic acid can sensitively inhibit the discoloration reaction or slow the reaction rate. The kinetic beha- vior of the inhibition reaction has been investigated and a kinetic spectrometric method for determination of trace oxalic acid was developed with detection limit 2.8×10 -8 g/mL and the linear range of the determination was 0~8×10 -7 g/mL oxalic acid. ε 430=1.50×10 5 L/(mol·cm). The method has been satisfactorily applied to the determination of trace oxalic acid in fruits, greens and cereals.
【关键词】 阻抑作用;
动力学光度法;
草酸;
水果;
蔬菜;
粮食;
溴甲酚紫;
【Key words】 inhibition; kinetic-spectrophotometry; oxalic acid; fruit; greens; cereals; bromocresol purple;
【Key words】 inhibition; kinetic-spectrophotometry; oxalic acid; fruit; greens; cereals; bromocresol purple;
【基金】 国家科技攻关计划课题资助项目 (2 0 0 1BA5 0 3B0 4)
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2004年03期
- 【分类号】TS207
- 【被引频次】6
- 【下载频次】98