【摘要】 氨基硝基苯并二氧化呋咱 (ANBDF)可与二甲基甲酰胺 (DMF)形成稳定的分子加合物 (两者摩尔比为 1∶1) ,未见文献报道 .报道了该加合物的合成、晶体结构、晶体学数据和结构参数 .该加合物为淡黄色透明晶体 ,其中ANBDF与DMF分子以氢键结合 ,属单斜晶系 ,空间群P2 1 /n .更多还原

【Abstract】 A stable molecular adduct can be formed from aminonitrobenzodifuroxan (ANBDF) and DMF with molar ratio of 1∶1. It is a pale yellow transparent crystal characterized with monoclinic system and P2 1/n space group, a =1 3216(3) nm, b =0 66199(13) nm, c =1 5745(3) nm, β =102 80(3)°; V =1 3433(5) nm 3; Z =4; D c=1 618 g·cm -3 ; F (000) =672; μ =0 141 mm -1 . The molecules of ANBDF and DMF in the adduct are linked by hydrogen bonding.更多还原