【摘要】 用超声辐射催化方法 ,合成了C2 3 H19N2 SF3 O2 Zn(1) Zn(2 )C8H5SF3 O2 双核锌大杂环配合物 ,经IR ,1HNMR ,13 CNMR ,MS和元素分析表征 .通过波谱分析表明 ,Zn(1)采取dsp3 杂化与 1,2 二氮 5 ,8 二氧 3 ,4,10 ,11 双 (苯并 )环十四 13 三氟甲基 1 噻吩配位 ,Zn(2 )采取sp2 杂化与 1′ 噻吩 3′ 三氟甲基 1′ ,3′ 二丙酮配位 ,形成双核锌 (II)树状型配合物更多还原

【Abstract】 By ultrasonic catalysis a macroheterocyclic dinuclear complex of C 23H 19N 2SF 3O 2Zn(1)-Zn(2)C 8H 5SF 3O 2 was synthesized. The title compound was characterized by IR, 1H NMR, 13C NMR, MS and elemental analysis. It was found that both Zn(1) complexing to 1,5-diazo-8,12-dioxa-4-trifluoromethyl-2-(2-thiophenyl)-6,7,13,14-bibenzocyclotetradecane with dsp 3 hybrid orbitals and Zn(2) complexing to 2-(1,1,1-trifluoroaceyl) acetylthiophene with sp 2 hybrid orbitals produce a tree-like dinuclear complex of Zn(II).更多还原