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用掺杂法改进碳纳米管气敏传感器的机理

Lmproving SWNT Gas Sensors by Doping Atoms

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【作者】 袁悦华刘之景李兴旺

【Author】 YUAN Yue-hua~1,LIU Zhi-jing~1,LI Xing-wang~2 (1.Department of Modern Physics,University of Science and Technology of China,Hefei 230026,China2.Dept of water and Environment,Anhai Technilal College of Water Resources and Hydroelectric Power,Hefei 230601,China)

【机构】 中国科学技术大学近代物理系安徽水电技术学院水资源与环境工程系 安徽 合肥 230026安徽 合肥 230026安徽合肥 230601

【摘要】 碳纳米管气敏传感器在敏感性、选择性、操纵性等性能上,远胜于传统的金属氧化物膜传感器。但由于受本征碳纳米管(纯净碳纳米管)吸附能力的限制,碳纳米管气敏传感器能检测的气体种类很少。斯坦福大学的ShuPeng等人的实验发现,掺杂了B、N原子的碳纳米管第一次成功地检测出了CO和H2O分子。在详细阐述碳纳米管传感器工作机理的基础上,用半导体杂质理论和离子对吸附模型对这一最新实验结果作出理论解释。这种掺杂方法,很有可能从根本上解决碳纳米管气敏传感器检测范围小的问题。

【Abstract】 Single-walled carbon nanotube(SWNT)gas sensor is much more advanced than the traditional metal-oxide sensor in terms of sensitivity,selectivity,maneuverability,and so on.But only a few kind of gases can be detected by SWNT sensor because of the limited adsorption ablity of intrinsic carbon nanotubes(CNTS).Currently,Shu Peng and his coworkers have found that CNTs doped with B and N atoms are able to detect H2O and CO molecules,respectively.The Theory of Semiconductor Impurities along with an ion-pair model is used to explain this new experiment phenomenon,based on detailed discussion of the mechanism of SWNT sensors.Doping CNTs with impurity atoms maybe a key method for solving the problem of SWNT sensors.

  • 【文献出处】 仪表技术与传感器 ,Instrument Technique and Sensor , 编辑部邮箱 ,2004年10期
  • 【分类号】TP212
  • 【被引频次】18
  • 【下载频次】479
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