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稀土对AlTiC细化剂组织及细化效果的影响

Effect of Rare Earths on Structure and Refining Efficiency of AlTiC Refiner

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【作者】 胡宪正梁超于金谈荣生曾宇乔蒋建清

【Author】 Hu Xianzheng, Liang Chao, Yu Jin, Tan Rongsheng, Zeng Yuqiao, Jiang Jianqing~ (Department of Material Science and Technology, Southeast University, Jiangsu 210098, China)

【机构】 东南大学材料科学与工程系东南大学材料科学与工程系 江苏南京210096江苏南京210096江苏南京210096

【摘要】 应用自蔓延高温合成法制备出含稀土及不含稀土两种AlTiC细化剂。应用扫描电镜及X射线衍射等手段分析了中间合金及细化剂的成分、组织和形貌。结果表明:稀土对反应合成TiC微细颗粒具有重要的促进作用,添加稀土明显加快反应速度;在AlTiCRE细化剂中,由于稀土的作用,改变了TiAl3和TiC的形态和分布,减小了TiC的聚集倾向,细化了TiC颗粒尺寸,从而增加了形核基底数。AlTiCRE细化晶粒的效果优于AlTiC,而且稀土还具有明显细化枝晶组织的作用。

【Abstract】 Two type refiners, in which one contains rare earths and the other without, were prepared with self-propagating high-temperature synthesizing method. The composition, microstructure and morphologies of master alloys and refiners were investigated with scanning electron microscopy (SEM) and X-ray diffraction (XRD). Experimental results indicate that rare earth presents obvious effect to promote the reaction synthesizing of TiC super-fine grains and accelerate reaction velocity. The existing of rare earths affects the morphologies and distributing of the TiAl3 and TiC, restrains the congregating tendency of TiC, and refines its granularity. AlTiCRE refiner shows obvious advantages over AlTiC refiner and evident effects on refining dendvite crystal.

【基金】 国家九五重点科技攻关项目(99 A30 02 07);江苏省十五攻关项目(BG2000011 3)
  • 【文献出处】 中国稀土学报 ,Journal of The Chinese Rare Earth Society , 编辑部邮箱 ,2004年02期
  • 【分类号】TG115
  • 【被引频次】64
  • 【下载频次】256
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