节点文献
2,2-二氯-1,3-苯并二氧噁茂与某些伯醇的反应性研究
Studies on reaetivity of 2,2-dichloro-l,3-benzodioxole with primary alcohols
【摘要】 2 ,2 -二氯 - 1,3-苯并二氧口恶茂与伯醇反应生成邻苯二酚碳酸酯和相应的氯代烷 ,氯代烷的产率从 2 0 %~97% ,取决于反应的摩尔比。对可能影响反应的因素如温度和反应时间也进行了探讨 ,结果表明 ,温度对反应产率的影响不很明显。
【Abstract】 The reaction of 2,2-dichloro-l,3-benzodioxole reacting with primary walcohols can produce o-phenylene carbonate and corresponding chloroalkanes. And the yields of chloroalkanes are 20-97% which depend on the molar ratios of reactants. Other factors influencing the reaction such as temperature and time were investigated. The results show that the yields not change evidently as the temperature variables.
【关键词】 2,2-二氯-1,3-苯并二氧口恶茂;
伯醇;
氯代烷;
反应活性;
【Key words】 dichloro-1,3-benzodioxole; primary alcohols; chloroalkanes; reactivity;
【Key words】 dichloro-1,3-benzodioxole; primary alcohols; chloroalkanes; reactivity;
【基金】 湖南省“十五”重点学科项目资助 (编号 :湘教通 [2 0 0 1] 179号 )
- 【文献出处】 湘潭师范学院学报(自然科学版) ,Journal of Xiangtan Normal University (Natural Science Edition) , 编辑部邮箱 ,2004年04期
- 【分类号】O621
- 【被引频次】2
- 【下载频次】74