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质子交换膜燃料电池用全氟磺酸复合膜性能研究

Research on perfluorsulfonic acid composite membrane for proton exchange membrane fuel cell

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【作者】 张海林岳瑞娟耿东森赵敏丽李培金

【Author】 ZHANG Hai-ling YUE Rui-juan GENG Dong-sen ZHAO Min-li LI Pei-jin (College of Material Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China)

【机构】 北京化工大学材料科与工程学院北京化工大学材料科与工程学院 北京100029北京100029

【摘要】 以醇和水为混合溶剂,在高温高压下制得了全氟磺酸树脂回收液,并用 FYPFSA 溶液改善了回收液的成膜性能,然后以 FIFE 多孔膜为增强材料,制成全氟磺酸/PTFE 复合膜用于质子交换膜燃料电池,对复合膜的物理化学性能和电化学性能进行了测定。在41.5℃、p(H2)=0.03 MPa、p(O2)=0.2 MPa 条件下用复合膜 CM1组装的电池最大功率密度达到0.4 W/cm2

【Abstract】 The scrap perfluorsulfonic acid ion exchange membrane was dissolved in the combined solvent of water and al- cohol at high temperature and high pressure,and the reclaimed perfluorsulfonic acid resin solution was so obtained.FYPFSA so- lution was introduced to improve the film forming property of the reclaimed perfluorsulfonic acid resin solution.A perfluorsulfonic acid composite membrane was prepared with mixed perfluorsulfonic acid resin solution and PTFE as a substrate.The chemical performance and electrochemical perfomance of the composite menthrane were also studied.One of the composite films(named CM1)has a max power density of 0.4 w/cm2 at 41.5℃ when p(H2)=0.03 MPa and p(O2)=0.2 MPa.

【关键词】 质子交换膜燃料电池FYPFSA 溶液PTFE复合膜
【Key words】 PEMFCFYPFSA solutionPTFEcomposite membrane
  • 【文献出处】 现代化工 ,Modern Chemical Industry , 编辑部邮箱 ,2004年S1期
  • 【分类号】TM911.4
  • 【被引频次】4
  • 【下载频次】248
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