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聚醚酰亚胺的性能改进

Improvement on properties of polyetherimides

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【作者】 孙彩霞王复东马磊徐杰刘晓海王爱琴张涛

【Author】 SUN Cai-xia WANG Fu-dong MA Lei XU Jie LIU Xiao-hai WANG Ai-qin ZHANG Tao (1.Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China;2.Ganjingzi Branch of Dalian Environmental Protection Bureau,Dalian 116031,China)

【机构】 中国科学院大连化学物理研究所大连市环境保护局甘井子分局中国科学院大连化学物理研究所 辽宁 大连116023辽宁 大连116023辽宁 大连116031

【摘要】 从耐热性、耐溶剂性、抗冲击性、阻燃性和加工流动性等方面概述了聚醚酰亚胺的性能改进进展。将不同结构的二酐混合后与二胺进行共缩聚反应,不仅可以提高聚醚酰亚胺的热稳定性,还可以改善其耐溶剂性;在聚醚酰亚胺中加入冲击改进剂或与耐冲击性较好的聚合物共混,可增强聚醚酰亚胺的抗冲击性能;为了进一步提高聚醚酰亚胺的阻燃防火性能,可以在聚醚酰亚胺树脂中添加氧化钼、氧化硅、氧化钛等氧化物,也可以将聚醚酰亚胺与三聚氰胺混合;在聚醚酰亚胺中加入少量的聚有机硅氧烷可以有效地改善聚醚酰亚胺的加工流动性。改性后的聚醚酰亚胺性能更加完善,用途更加广泛。

【Abstract】 Polyetherimides(PEIs)are a known class of polymers used as industrial resins.The improvement of PEIs in heat and solvent resistance,impact resistance,flame retardance and flow processing characteristic was reviewed.PEIs which are so prepared by intercondensation of aryl diamine and dianhydride mixture have improved the thermal stability and solvent resis- lance of themselves.Mixing PEIs with impact modifier or the polymers with excellent impact property has dramatic increases in impact resistance of PEIs without sacrificing the other properties.In order to achieve increases in flame retardance,oxide of molybdelium,silica titanium dioxide or melamine can be added into the PEIs.Polyorgane siloxanes can improve the flow charac- teristics of PEIs.Modified PEIs have higher performance and more applications.

  • 【文献出处】 现代化工 ,Modern Chemical Industry , 编辑部邮箱 ,2004年S1期
  • 【分类号】TQ317
  • 【被引频次】11
  • 【下载频次】698
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