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准二维电荷密度波导体钾紫青铜K_xMo₆O₁₇单晶样品的制备

Crystal growth of quasi-two-dimensional purple bronze K_xMo₆O₁₇

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【作者】王俊峰；熊锐；余恒；李慧；汤五丰；余祖新；石兢；田德诚；田明亮；张裕恒；

【Author】 Wang Jun-Feng 1) Xiong Rui 1) Yu Heng 1) Li Hui 1) Tang Wu-Feng 1) Yu Zu-Xin 1) Shi Jing 1)2) Tian De-Cheng 1) Tian Ming-Liang 3) Zhang Yu-Heng 3) 1)(Department of Physics,Wuhan University,Wuhan 430072,China) 2)(International Center for Materials Physics,Chinese Academy of Sciences,Shenyang 110016,China) 3)(Structure Research Laboratory,University of Science and Technology of China, Hefei 230026,China)

【机构】武汉大学物理科学与技术学院；中国科学技术大学结构分析中心；中国科学技术大学结构分析中心武汉430072；武汉430072；武汉430072；中国科学院国际材料物理中心；沈阳110016；合肥230026；合肥230026；

【摘要】采用碳酸盐替代高钼酸盐电解还原的方法成功制备出了准二维电荷密度波导体钾紫青铜单晶 .通过x射线衍射、透射电子显微术等方法对单晶进行结构分析表明 :晶胞参数a =b =0 5 5 4 0nm ,c =1 35 0 8nm ,单晶为三角晶系 ,对称群为P3- .电阻温度关系曲线的测量显示 :钾紫青铜KxMo6 O1 7单晶在 112K附近发生金属到金属的Peierls相变更多还原

【Abstract】 Purple bronze K xMo 6O 17 single crystals are successfully grown by electrolytic reduction method from the melts of K 2CO 3 and MoO 3.The detailed process of the preparation is reported.The structure of the single crystals are investigated with x-ray diffraction and Transmission electron microscope.The results show that the crystals have large sizes and high qualities.The unit cell parameters are:a=b=0.5540nm,c=1.3508nm,and the crystal structure is refined to be trigonal with space group P3-.The temperature dependence of resistance reveals that the compounds undergo Peierls phase transition at 112K.更多还原