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四水合碳酸镁铵的合成及晶体结构
Synthesis and crystal structure of magnesium ammonium carbonate tetrahydrate
【摘要】 对于碳酸镁铵的合成,通过查相关资料,前人仅制得该物质的粉末晶体,并未见有合成单晶的报道。利用六水氯化镁和碳酸铵在一定的温度和浓度下合成了四水合碳酸镁铵单晶。并通过元素分析及X-射线单晶衍射法,测定了该化合物的晶体结构。
【Abstract】 Only the powder crystal of ammonium magnesium carbonate tetrahydrate prepared was reported in previous literature,but there was no report on the synthesis of its single crystal.A single crystal of ammonium magnesium carbonate tetrahydrate has been synthesized under certain specific temperature and concentration using magnesium chloride hexhydrate and ammonium carbonate as starting materials.The crystal structure of the compound has been determined by elemental analysis and X-ray single-crystal diffraction.
【关键词】 四水合碳酸镁铵;
单晶;
氧化镁;
碳酸铵;
【Key words】 magnesium ammonium carbonate tetrahydrate; single crystal; magnesium chloride; ammonium carbonate;
【Key words】 magnesium ammonium carbonate tetrahydrate; single crystal; magnesium chloride; ammonium carbonate;
【基金】 河北省基金项目;编号296172。
- 【文献出处】 无机盐工业 ,Inorganic Chemicals Industry , 编辑部邮箱 ,2004年05期
- 【分类号】O782
- 【被引频次】3
- 【下载频次】220