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一维链配位聚合物[Mn（acacen）{N（CN）₂}]_n的合成、结构和性质的研究（英文）

Synthesis,Structure and Property of One-dimensional Chain Coordination Polymer [Mn（acacen）{N（CN）₂}]_n

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【Author】 WANG Shou-Wu1,2 ZHOU Jun-Hui1 LI Bao-Long*,1 ZHANG Yong1(1Key Laboratory of Organic Synthesis of Jiangsu Province,College of Chemistry and Chemical Engineering,Suzhou University,Suzhou 215006)(2Donggang College,Huaihai Institute of Technology,Lianyuangang 222069)

【机构】苏州大学化学化工学院江苏省有机合成重点实验室；苏州大学化学化工学院江苏省有机合成重点实验室苏州215006淮海工学院东港学院；连云港222069；苏州215006；苏州215006；

【Abstract】 The manganese(II) complex [Mn(acacen){N(CN)2}]n [H2acacen=bis(acetylaceton e )ethylenediimine] has been synthesized and the structure has been determined. Th e complex forms a one-dimensional chain structure via the bidentate bridge ligan d -linking [Mn(acacen)] moiety. The magnetic property of the comp ound (75~300 K) shows the existence of an antiferromagnetic exchange interaction among paramagnetic centers along the chain. CCDC: 244940.更多还原

【关键词】晶体结构；一维链；锰配合物；二氰氨基；
【Key words】 crystal structure one-dimensional chain manganese complex dicyanamide；

【基金】江苏省高校自然科学基金(No.03KJB150118);江苏省有机合成重点实验室开放基金资助项目