节点文献
噻吩甲酰基吡唑啉酮缩氨基酸稀土配合物的合成、表征及生物活性
Synthesis, Characterization and Bioactivity of Rare Earth Complexes of Thenoylpyrazolone-amino-acid
【Abstract】 A new amino-acid Schiff base, 1-phenyl-3-methyl-4-(2-thenoyl) pyrazolone-5-β-alanine (HL) and its ten rare earth complexes have been synthesized. On the basis of elemental analysis and molar conductance, the general formula of the complexes, ·nH2O (RE=La, Nd, Eu, Tb, Y, n=2; RE= Pr, Sm, n=1; RE= Dy, Er, Yb, n=3), is given. They were characterized by IR, UV-visible, 1H NMR, 13C NMR and fluorescence. The results show that the rare earth ions exhibit coordination of eight in the complexes.The antibacterial experiments indicate that they have high antibacterial activities against S. Aureus, B. Subtillis, E. Coli, E. Carotovora and C. Flaccumfaciens.
【关键词】 稀土;
噻吩甲酰基吡唑啉酮缩氨基酸;
席夫碱;
配合物;
生物活性;
【Key words】 rare earths thenoylpyrazolone-amino-acid Schiff base complex bioactivity;
【Key words】 rare earths thenoylpyrazolone-amino-acid Schiff base complex bioactivity;
【基金】 教育部重点科研基金(No.02053);黑龙江省自然科学基金(No.B01鄄06);省高校骨干教师创新计划资助项目。
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2004年08期
- 【分类号】O641.4
- 【被引频次】26
- 【下载频次】308