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层柱人工水热合成皂石的制备与表征(英文)

Synthesis and Characterization of Alumina Pillared Synthetic Saponite

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【作者】 姚铭刘子阳王凯雄李彩今邹永存孙红杰

【Author】 YAO Ming1 LIU Zi-Yang*,1 WANG Kai-Xiong1 LI Cai-Jin2 ZOU Yong-Cun2 SUN Hong-Jie1(1Department of Chemistry, Zhejiang University, Hangzhou 310027)(2Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023)

【机构】 浙江大学化学系吉林大学无机合成与制备化学国家重点实验室浙江大学化学系 杭州310027杭州310027长春130023杭州310027

【摘要】 利用具有理想皂石结构的人工水热合成蒙皂石为层原料,通过与羟基聚合铝离子([Al13O4(OH)24(H2O)12]7+)交换反应合成得到了一种层柱粘土。实验对于该铝柱皂石进行了粉末XRD,FT鄄IR和TG鄄DTA表征。氮气吸附实验说明其高温活化(773K,2h)产物具有很高的BET比表面(360m2·g-1)。相对于层柱蒙脱土,层柱皂石显示了更高的催化裂解性能和热稳定性。层柱皂石的异丙苯裂解转化率达到了65%;而层柱蒙脱土的转化率只有4%。这说明层材料的四面体取代对于层柱粘土Br觟nsted酸位的形成具有重要的决定作用。氨程序升温脱附实验发现铝柱皂石在350~650℃区间具有较强的氨脱附量,表明层柱皂石具有层柱蒙脱土所没有的强酸中心。

【Abstract】 Alumina pillared clay was synthesized by a cationic exchange reaction with [Al13O4(OH)24(H2O)12]7+ (referred to as Al13) using synthetic smectite with ideal saponite structure as parent material. The obtained pillared saponite was characterized by X-ray powder diffraction, FT-IR and TG-DTA. The pillared materials showed a very high BET surface area of 360 m2·g-1 by N2 adsorption at 77 K after calcination at 773 K for 2 hours. Compared with the alumina pillared montmorillonite, the pillared saponite exhibited higher cracking activity and better thermal stability. The cumene conversion was ca. 65% over the pillared saponite by the impulse reaction, while it was only ~4% for the pillared montmorillonite, indicating that the substitutions in the tetrahedral sheets played an important role in the development of Br?觟nsted acidity of the catalyst. By temperature programmed desorption of ammonia (TPDA), pillared saponite showed high strong acidity in the temperature range 350~650℃.

【基金】 中国石化公司(No.X502034);国家自然科学基金(No.20247001)资助项目。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2004年08期
  • 【分类号】O643.3
  • 【被引频次】12
  • 【下载频次】108
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