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N,N’-双(2-吡啶乙基)二硫代草酰胺根桥联的三核铜(Ⅱ)配合物的合成及性质

Syntheses and Properties of Trinuclear Copper(Ⅱ) Complexes Bridged with N,N′-Bis(2-pyridylethyl)-Dithiooxamidate

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【作者】 崔建中程鹏廖代正姜宗慧阎世平王耕霖

【Author】 CUI Jian-Zhong*,1 CHENG Peng2 LIAO Dai-Zheng2 JIANG Zong-Hui2 YAN Shi-Ping2 WANG Geng-Lin*,2(1Department of Chemistry,Tianjin University,Tianjin 300072)(2Department of Chemistry,Nankai University,Tianjin 300071)

【机构】 天津大学化学系南开大学化学系南开大学化学系 天津300072天津300071天津300071

【Abstract】 Two Trinuclear copper(Ⅱ) complexes bridged with N,N′-Bis(2-pyridylethyl)-Dithiooxamidate, (ClO4)2 (1) and (NO3)2 (2) (H2L=N,N′-Bis(2-pyridylethyl)-Dithiooxamide), have been synthesized, and characterized by elemental analyses, IR, UV-Visible spectra, conductance and EPR spectra. The variable temperature magnetic susceptibility for complex 1 has been measured in the temperature range of 1.5~298 K. Experimental data of magnetic susceptibility are successfully fit to theoretical value based on the spin Hamiltonian operator: H=-2J(S1S2+ S2S3)-2JS1S3, S1=S2=S3=1/2, giving the magnetic exchange parameters of 2J=-221.6 cm-1 and 2j=-15.8 cm-1. This result indicates the presence of a strong antiferromagnetic spin exchange interaction between the Cu(Ⅱ) ions.

【基金】 国家自然科学基金资助项目(No.50173011);教育部留学回国人员科研基金
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2004年06期
  • 【分类号】O641.4
  • 【被引频次】1
  • 【下载频次】185
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