节点文献
N,N’-双(2-吡啶乙基)二硫代草酰胺根桥联的三核铜(Ⅱ)配合物的合成及性质
Syntheses and Properties of Trinuclear Copper(Ⅱ) Complexes Bridged with N,N′-Bis(2-pyridylethyl)-Dithiooxamidate
【Abstract】 Two Trinuclear copper(Ⅱ) complexes bridged with N,N′-Bis(2-pyridylethyl)-Dithiooxamidate, (ClO4)2 (1) and (NO3)2 (2) (H2L=N,N′-Bis(2-pyridylethyl)-Dithiooxamide), have been synthesized, and characterized by elemental analyses, IR, UV-Visible spectra, conductance and EPR spectra. The variable temperature magnetic susceptibility for complex 1 has been measured in the temperature range of 1.5~298 K. Experimental data of magnetic susceptibility are successfully fit to theoretical value based on the spin Hamiltonian operator: H=-2J(S1S2+ S2S3)-2JS1S3, S1=S2=S3=1/2, giving the magnetic exchange parameters of 2J=-221.6 cm-1 and 2j=-15.8 cm-1. This result indicates the presence of a strong antiferromagnetic spin exchange interaction between the Cu(Ⅱ) ions.
【Key words】 dithiooxamide bridging ligand trinuclear copper(Ⅱ) complex magnetic properties;
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2004年06期
- 【分类号】O641.4
- 【被引频次】1
- 【下载频次】185