节点文献
铜配位聚合物[Cu（C5H6S5）（SCN）]∞的合成和结构研究（英文）
Synthesis and Crystal Structure of a Copper(Ⅰ) Coordination Polymer with 4,5-bis(methylthio)-1,3-dithiole-2-thione Ligand
【Abstract】 The Copper(Ⅰ) supramolecular complexes of 4,5-bis(methylthio)-1,3-dithiole-2-thione (C5H6S5), [Cu(C5H6S5)(SCN)]∞ 1 and [Cu(C5H6S5)I]∞ 2, have been prepared and characterized. X-ray structure analysis for complex 1 reveals that the infinite chain structure with polymeric stairs of different lengths is formed through the coordination mode (μ3) of the thiocyanate bridges. The shorter interchain S...S contacts give rise to a three-dimensional network structure. CCDC: 215668.
【关键词】 铜配合物；
晶体结构；
配位聚合物；
超分子；
多硫配合物；
【Key words】 copper complexes crystal structures polymeric complexes supramolecular complexes thione complexes；
【Key words】 copper complexes crystal structures polymeric complexes supramolecular complexes thione complexes；
【基金】 国家自然科学基金资助项目(No.NSF20201006,90101028)。
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2004年05期
- 【分类号】O631
- 【被引频次】3
- 【下载频次】161