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苯甲酰丙酮存在下含水体系中合成二茂钛取代水杨酸配合物

Preparation of Titanocene Substituted Salicylate Complexes in Aqueous Media in the Presence of Benzoylacetone

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【作者】 韩丽高子伟高玲香孙平王宗慧王峰

【Author】 HAN Li GAO Zi - Wei GAO Ling - Xiang SUN Ping WANG Zong - Hui WANG Feng(College of Chemistry and Materials Science,Shaanxi Normal University,Xi’an710062)

【机构】 陕西师范大学化学与材料科学学院陕西师范大学化学与材料科学学院 西安710062西安710062西安710062

【Abstract】 Four titanocene complexes were prepared in aqueous or two - phase medium by the reaction of benzoylacetone titanocene with substituted salicylic acid,respectively.Based on the UV - Vis spectra,we studied the accelerating effect of the benzoylacetone on the reaction rate quantificationally.The results demonstrated that the presence of it not only stabilizes the “ Cp 2 Ti ” species and accordingly makes pH value of the aqueous solution of substituted salicylic acid increased but also prompts the reaction due to the presence of its conjugation structure and oleophyllic group.Furthermore,the presence of benzoylacetone is in favor of the simplification of the products.

【基金】 国家自然科学基金资助项目(No.20101005);陕西省自然科学基金资助项目(No.2003B04);陕西师范大学校级重点科研项目。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2004年04期
  • 【分类号】O641.4
  • 【被引频次】11
  • 【下载频次】188
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