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LiCoO2对LiMn2O4改性过程的研究

Studies on Process of LiMn2O4Modified by LiCoO2

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【作者】 卢世刚李明勋黄松涛蔡振平颜广炅金维华

【Author】 LU Shi - Gang LI Ming - Xun HUANG Song - Tao CAI Zhen - Ping YAN Guang - Jiong JIN Wei - Hua(General Research Institute of Non-ferrous Metals,Beijing100088)

【机构】 北京有色金属研究总院矿冶所北京有色金属研究总院矿冶所 北京100088北京100088北京100088

【Abstract】 Modified lithium manganese oxides were prepared by using LiMn 2 O 4 and LiCoO 2 as precursors by solid state reaction.A study has been carried out by TG - DSC,XRD and FTIR to analyze the reaction process and structural characterization of products.The results showed that the LiMn 2 O 4 reacted chemically with LiCoO 2 at high temper - ature.Li and Co atom could insert into the LiMn 2 O 4 crystal lattice and obtained the Cobalt - Doped spinel com - pound.The results of constant - current cyclic test showed that the cyclic stability of the products are increased with the amount of doped LiCoO 2 ,while their initial capacity is decreased.

【基金】 国家自然科学基金资助项目(No.50074012)。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2004年04期
  • 【分类号】O614
  • 【被引频次】6
  • 【下载频次】124
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