【Abstract】 The complex of[N,N,N ’ ,N ’- tetrakis(2 - benzimida zolyl methyl) - 1,4 - diethylene amino] - glycol ether(EGTB)with zinc (Ⅱ) ,[Zn 2 (EGTB)Cl 2 ](ClO 4 ) 2 · CH 3 OH · 3H 2 O was synthesized and characterized with element analysis,UV and IR spectroscopy,and X - ray diffraction method.The crystal belongs to monoclinic with space group of P2 1 /c.The cell parameters are a=1.4376(2)nm,b=2.52650(4)nm,c=1.43531(2)nm,β =101.7037(8) ° ,Z=4,F(000)=2376,D c =1.503g · cm -3 ,The final R=0.0804,wR 2 =0.2236.Biological activities of the complexe was traced by UV - Vis spectrum.The result demonstrates that the complexe has good catalytic abliliy.CCDC:180994.更多还原