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NaY固载酒石酸钛配合物的研究

Studies on NaY Encapsulated Titanium Tartrate Complex

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【作者】 吕爱霞伏再辉尹笃林徐友志明杜鹃阳清银董红

【Author】 LU Ai-Xia FU Zai-Hui* YIN Du-Lin XU You-Zhi MING Du-Juan YANG Qing YIN Dong-Hong(College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081)

【机构】 湖南师范大学化学化工学院湖南师范大学化学化工学院 长沙410081长沙410081长沙410081

【Abstract】 Titanium tartrate complex has been embedded into the super-cage of NaY zeolite carriers by using a "ship-in-bottle" method, which was confirmed by FT-IR. and UV-Vis diffuse reflection spectra . In catalyzing the epoxidation of cinnamyl alcohol with TBHP as an oxidant, Ti complex encapsulated into NaY showed the high catalytic turnover numner and the better selectivity for the epoxides than Ti complex grafted onto HMS. The reused test indicated that NaY-Ti-DET possessed the excellent stability, and could be recovered and repeatedly used many times without being loss of activity.

【基金】 国家自然科学基金资助项目(No.29773013);湖南省自然科学基金资助项目(No.[湘计科字-2000]-237-00JJY201)。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2004年03期
  • 【分类号】O641.4
  • 【被引频次】2
  • 【下载频次】111
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