【摘要】 在室温下,MnSO4·H2O和1,2,4-苯三甲酸穴H3BTC雪反应得到化合物眼Mn穴H2BTC(2(H2O(4[·2H2O)1(化合物1和CuSO4·5H2O反应得到化合物眼Cu穴HBTC雪穴H2O雪1.5演·H2O穴2雪。化合物1是一个单核分子化合物。在化合物1中熏每个锰离子和两个H2BTC-离子及四个水分子配位。化合物2中熏每个铜离子和三个HBTC2-及两个水分子配位熏其中的一个水分子起桥联作用从而形成二维网状结构。更多还原

【Abstract】 A new coordination polymer[Cu(HBTC)(H2O)1.5]·H2O(2)was synthesized by reaction of CuSO4·5H2O with a mononuclear complex[Mn(H2BTC)2(H2O)4]·2H2O(1)which was obtained by the reaction of MnSO4·H2O with1,2,4-benzenetricarboxylic acid(H3BTC).The complexes1and2were characterized by X-ray crystallography.In complex1,each Mn(Ⅱ)atom is coordinated by two H2BTC-units and four water molecules;while in complex2,each Cu(Ⅱ)atom is coordinated by three HBTC2-units and two water molecules,one of which acts as a bridge,to generate an infinite2D network.CCDC:1,214714;2,214715.更多还原