【摘要】 合成了两种新的双苯基硫脲二苯并 18 冠 6冠醚(L1,L2),研究了它们对NaH2PO4·2H2O,KH2PO4,KHSO4,KNO3,KHCO3等无机盐的识别能力,并用红外光谱、核磁共振氢谱、X 射线粉末衍射分析等方法对配合前后进行了表征.结果表明对这些无机盐而言L2的配合能力优于L1,L1与L2有类似的识别次序:KH2PO4>NaH2PO4>KHSO4>KNO3 KHCO3.更多还原

【Abstract】 Two novel bis（phenyl thiourea） DB-18-C-6（L₁,L₂） have been synthesized. The recognition of L₁,L₂ to NaH₂PO₄ 2H₂O, KH₂PO₄, KHSO₄, KNO₃ and KHCO₃ has been studied via IR,¹H NMR and XRD. The data indicate that the binding capacity of L₂ is better than that of L₁, and they bound ions with a same selectivity in the order of KH₂PO₄>NaH₂PO₄>KHSO₄ >KNO₃KHCO₃.更多还原