【摘要】 对势模型进行变形,借助超维里定理和Hellman-Feyman定理,不用求波函数,而只根据零级能量和势模型推导了无波函数微扰论的递推公式.利用这些公式和双变量的快速逼近的pad埁近似方法,计算了Hcl分子的振动能谱,计算结果与实验相符.更多还原

【Abstract】 This paper changed the potential model,derived the recurrence fourmula of the perturbation theory without wave function based on Hypervirial theorem and Hellman-Feyman theorem,then computed the vibration spectrum of Hcl molecule by using this formula and the two-variable Padè approximation method.The results are well accorded with the experimental values.更多还原