节点文献

车用液化石油气气路系统中残留物的组成

COMPOSITION OF RESIDUES FORMED IN THE AUTO-LPG FUEL FLOW SYSTEM

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 吴明清仇延生潘光成张红霞李军

【Author】 WU Ming-qing~1, QIU Yan-sheng~1, PAN Guang-cheng~1, ZHANG Hong-xia~1, LI Jun~2 (1. Research Institute of Petroleum Processing,SINOPEC,Beijing 100083,China; 2. Beijing Yanshan Petrochemical Company,Beijing 102500,China)

【机构】 中国石油化工股份有限公司石油化工科学研究院北京燕山石化公司 北京100083北京100083北京102500

【摘要】 影响车用液化石油气(Liquefiedpetroleumgas,简称LPG)推广使用的主要因素之一是气路系统中的堵塞物。对车用液化石油气气路系统中堵塞物的研究结果表明,蒸发器上的残留物主要是酯类、醚类、正构烷烃、单质硫和硫化铜粉末。其中酯类、醚类是相关橡胶材料中的添加剂,显然是烃类长期浸泡腐蚀的结果;正构烷烃是尾气再循环气中的CO和CH通过F T(Fischer Tropsch)反应合成而得;单质硫则来源于LPG中溶解的单质硫。过滤器中的堵塞物是未能通过过滤器的颗粒状硫化铜,与蒸发器中的粉末状硫化铜均来源于LPG中的活性硫对铜制管线的腐蚀。烃类的碳链越长,对橡胶的腐蚀性越强。

【Abstract】 The formation of residues in the auto-LPG fuel system is one of the main obstacles in the application of LPG as vehicular fuel. It was testified that most of the residues in LPG evaporators were additives extracted from rubber devices in the evaporator by LPG, normal paraffin or wax which were synthesized by CO and CH through F-T reaction in Wen’s tube and air-fuel mixture chamber. Elemental sulfur was accumulated from the trace sulfur dissolved in LPG itself. The powder of copper sulfide was produced through the corrosion of copper by corrosive sulfur in LPG, passing the filter to the evaporator. Black granular substance in the filter was copper sulfide failed to pass the filter. The longer the carbon chain the hydrocarbon has, the serve the erosion the rubber been countered in the auto-LPG fuel system.

  • 【文献出处】 石油学报(石油加工) ,Acta Petrolei Sinica (Petroleum Processing Section) , 编辑部邮箱 ,2004年03期
  • 【分类号】U491.9
  • 【被引频次】3
  • 【下载频次】76
节点文献中: 

本文链接的文献网络图示:

本文的引文网络