【摘要】 使用CuCl 四甲基乙二胺络合物催化β 萘酚氧化偶联,联萘酚产率可达80%以上。考察了金属盐种类、配体用量对联萘酚产率的影响。当采用手性配体L 尼古丁或(1S,2R) 盐酸麻黄碱时,联萘酚产率中等,光学收率较低。更多还原

【Abstract】 CuCl-tetramethylethylenediamine complex was used to catalyze the oxidative coupling reaction of β-naphthol, the yield of binaphthol may up to 80%. The effects of the type of metal-salt and the dosage of ligand were studied. When L-nicotine or (1S,2R)-ephedrine hydrochloride was used as chiral ligand, binaphthol was achieved in modest yield and low optical yield.更多还原