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纳米CaCO3/EPO/PP复合材料性能与结构的研究

Study on Property and Structure of Nano-meter CaCO3/EPO/PP Composite

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【作者】 俞江华王国全王文一陈建峰曾晓飞

【Author】 YU Jiang-hua 1, WANG Guo-quan 1, WANG Wen-yi 1, CHEN Jian-feng 2, ZENG Xiao-fei 2 (1. Institute of Material Sci. and Eng.,Beijing University of Chemical Technology, Beijing 100029, China;2. Research Center of High Gravity Eng. and Tech., Ministry of Education,Beijing University of Chemical Technology,Beijing 100029, China)

【机构】 北京化工大学材料科学与工程学院北京化工大学教育部超重力工程研究中心北京化工大学教育部超重力工程研究中心 北京100029北京100029北京100029

【摘要】 研究了纳米CaCO3 /EPO/PP复合材料的力学性能、熔体流变性能及纳米CaCO3 粒子在PP基体中的分散状况。结果表明 :弹性体EPO对PP有很好的增韧效果 ,当EPO用量为 4份时 ,PP从脆性断裂转变成韧性断裂 ;当EPO用量为 10份时 ,PP复合材料的室温和低温缺口冲击强度均有大幅度的提高。在EPO/PP复合材料中加入纳米CaCO3不仅可以显著提高复合材料的室温和低温缺口冲击强度 ,而且可显著提高复合材料的弯曲弹性模量和MFR ,改善复合材料的加工流动性能 ;纳米CaCO3 粒子在PP中达到了纳米级分散

【Abstract】 The mechanical and rheological properties of nano-meter CaCO 3/EPO/PP composites and the dispersion of nano-meter CaCO 3 in PP matrix were studied. The results showed EPO had good toughening effect on PP, when the content of EPO was 4 phr, PP changed from brittle fracture to tough fracture;when the content was 10 phr, the notched impact strength of the composite at room and low temperature increased greatly. The addition of nano-meter CaCO 3 to the EPO/PP composite could not only improve the impact strength at room and low temperature, but also the bending modulus and the MFR of EPO/PP blend, resulted in improving of the processability of the composite. CaCO 3 nano-meter particles were well dispersed in PP matrix at nano-meter scale.

【基金】 国家“十五”重大科技攻关项目 (2 0 0 2 -CC -0 1);教育部重大科技研究基金项目(重大 0 2 0 2 )
  • 【文献出处】 塑料工业 ,China Plastics Industry , 编辑部邮箱 ,2004年11期
  • 【分类号】TQ325.14
  • 【被引频次】4
  • 【下载频次】164
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