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液膜法处理硫酸工业废催化剂

Waste Catalysts Recovering with Liquid Film Method in Surphuric Acid Industry

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【作者】 廉宜君; 全会玲; 张海燕;

【Author】 LIAN Yi-jun~1 , QUAN Hui-lin~2, ZHANG Hai-yan~1 (1 Department of Chemistry, Teachers College, Shihezi University, Shihezi, X injiang 832003, China; 2 Xiangfan Hongwei Medical & Chemical Co. Ltd, Xiangfan, Hubei 441021, China)

【机构】 石河子大学师范学院化学系; 红卫医药化工有限责任公司; 石河子大学师范学院化学系 新疆 石河子 832003; 湖北 襄樊 441021; 新疆 石河子 832003;

【摘要】 利用冠状液膜法回收硫酸工业废催化剂中的V2O5,探求了液膜法提取的最佳条件,实验研究了载体浓度、油水相比、pH值、迁移时间和反萃液的浓度对钒迁移率的影响。结果表明,在载体浓度为5%,液膜环境为pH=3.0,迁移时间为5min,油水比为1:3,反萃液中氯化铵浓度为6mol/L时,钒的迁移率可达97%。

【Abstract】 In this paper, the reclamation of vanadium pentoxide from waste catalysts of the sulphurie acid industry was discussed. Test study was made on the liquid film extraction condition preliminarily, such as carrier concentration, ratio between oil and water,pH of stuff liquid, migrating time,stripping agent concentration.The results indicated that carrier concentration is 5%, ratio between oil and water is 1:3, pH of stuff liquid is 3.0, migrating time is 5 min, stripping agent concentration is 6mol/L. Under these conditions the minration percentage achieves 97%.

【关键词】 液膜法; 萃取; 催化剂; V2O5;
【Key words】 crown liquid film; extra; catalysts; vanadium pentoxide;
  • 【文献出处】 石河子大学学报(自然科学版) ,Journal of Shihezi University(Natural Science) , 编辑部邮箱 ,2004年03期
  • 【分类号】X781
  • 【下载频次】93
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