【摘要】 用4,4’ 联吡啶分别与高氯酸银、磷酸二氢银反应,得到了化合物[Ag(4,4’ bipyri dine)]ClO41和[Ag(4,4’ bipyridine)]H2PO4·2H2O2,通过单晶X射线衍射对它们的结构进行了确证.数据为:1三斜晶系,P 1空间群,Mr=363.50,a=8.181(8),b=8.747(4),c=8.921(7) ,α=80.35(1),β=74.64(1),β=73.48(1)o,V=587.2(8) 3,Z=2,F(000)=356,Dc=2.056g·cm-3,μ=1.951mm-1,R1=0.0467,wR2=0.1301;2单斜晶系,P2/c空间群,Mr=397.07,a=8.566(6),b=8.807(7),c=18.729(17) ,β=101.37(1),V=1385.2(19) 3,Z=4,F(000)=792,Dc=1.904g·cm-3,μ=1.596mm-1,R1=0.0714,wR2=0.1834;结构分析表明,二者皆为一维链状结构.分子间通过静电引力、氢键使得化合物构成二维的超分子化合物.更多还原

【Abstract】 Two complexes, \ClO₄ 1 and \H₂PO₄·2H₂O 2, were obtained by selfassembly of AgX （X = ClO^-₄, H₂PO^-₄） with 4,4’bipyridine. Data: 1, Triclinic, P1, M _r = 363.50, a = 8.181（8）, b = 8.747（4）, c = 8.921（7） , α = 80.35（1）, β = 74.64（1）, β = 73.48（1）^o, V = 587.2（8） ³, Z = 2, F（000） = 356, D _c = 2.056 g·cm^-3, μ = 1.951 mm^-1, R₁=0.0467, wR₂=0.1301; 2, monoclinic, P2/c, M _r = 397.07, a = 8.566（6）, b = 8.807（7）, c = 18.729（17） , β = 101.37（1）, V = 1385.2（19） ³, Z = 4, F（000） = 792, D _c = 1.904 g·cm^-3, μ = 1.596 mm^-1, R₁=0.0714, wR₂ =0.1834; Xray singlecrystal diffraction shows that the compounds have a onedimensional chain structure, and the compounds are formed twodimensional construction by inter- or intramolecular hydrogen bonds and electrtrostatic forces in solid.更多还原