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不同水煤浆分散剂与煤之间的相互作用规律研究 Ⅴ.煤在分散剂水溶液中的溶出离子及其对CWS性质的影响

The interaction between different CWS dispersants and coals Ⅴ. Dissolved ions of coals in the aqueous solution of dispersants and their effects on CWS properties

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【作者】 邹立壮朱书全王晓玲

【Author】 ZOU Li-zhuang, ZHU Shu-quan, WANG Xiao-ling (School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing100083, China)

【机构】 中国矿业大学 北京 化学与环境工程学院中国矿业大学 北京 化学与环境工程学院 北京 100083北京 100083北京 100083

【摘要】 通过原子吸收和等离子体原子发射光谱法,研究了6种不同分散剂对14种煤溶出Ca2+、Mg2+、Fe3+(Fe2+)、Al3+、SiO2-3离子的影响。结果表明,煤中溶出高价离子的数量,主要取决于分散剂与高价离子间的相互作用特征,以及矿物质的种类和数量。煤在不同分散剂水溶液中溶出高价离子的多少,并不单纯与水煤浆(CWS)的流变性或煤的成浆性具有相关性。煤中矿物质对CWS性质的影响,是多种因素综合作用的结果,溶出离子的种类和数量只是其中的重要因素之一。

【Abstract】 The effects of 6 dispersants on the amounts of Ca2+, Mg2+, Fe3+(Fe2+), Al3+, and SiO2-3 ions extracted from 14 Chinese coals were studied by atomic adsorption spectrometry (AAS) and inductively coupled plasmatorch-atomic emission spectrometry (ICP-AES). The results show that many dispersants accelerated the dissolution of Ca2+ ion from coals, but were not obvious to that of Mg2+ and Al3+ ions. The influence of different dispersants on dissolved Fe3+/Fe2+ ion depends on the kinds of mineral matters in coal. The amounts of dissolved high-valence cations from coals mainly depend on the interaction between dispersants and coals, as well as the kinds and amounts of mineral matters in coals. There is no certain relativity between the amounts of dissolved cation and corresponding metal oxide in coal ash. The slurryability or rheological behavior of coal water slurry (CWS) is not simply dependent on the amounts of high-valence cations. The effect of mineral matters in coals on CWS properties is an integrated result of many factors, and the kind and amount of dissolved inorganic ions are only some of the important factors.

【关键词】 矿物质分散剂水煤浆溶出离子
【Key words】 coalmineral matterdispersantcoal water slurrydissolved ion
【基金】 国家自然科学基金(50074033)。~~
  • 【文献出处】 燃料化学学报 ,Journal of Fuel Chemistry and Technology , 编辑部邮箱 ,2004年04期
  • 【分类号】TQ53
  • 【被引频次】27
  • 【下载频次】413
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