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拜耳法种分附聚动力学初步研究
Preliminary study of agglomeration dynamics on crystalline particles in Bayer process
【摘要】 本文对拜耳法铝酸钠溶液种分附聚过程进行了研究 ,采用降温方式 ,利用最小二乘法求出附聚动力学方程为dC/dt=3 .14× 10 1 0 ×exp( -88.14× 10 3/RT)× (C -Ce) 2 ,表观活化能为 88.14kJ/mol。求得了不同温度下的分解速率常数能较好地符合阿仑尼乌斯公式
【Abstract】 The paper describes the agglomeration process of crystalline particles during precipitation in sodium aluminate solution of Bayer process.It derives aggglomeration dynamics formula dC/dt=3.4×1010×exp(-88.14×103/RT)×(C-Ce)2 with method of least squares in cooling down way.The aggarent activation energy is 88.14kJ/mol.The constant of precipitation rate derived under different temperatures can well match with Arrhenius formula.
- 【文献出处】 轻金属 ,Light Metals , 编辑部邮箱 ,2004年10期
- 【分类号】TF821
- 【被引频次】15
- 【下载频次】96