【摘要】 报道了新合成的二氰基二硫纶·菲咯啉 5 ,6 二酮合铜 (Ⅱ )配合物CuLL′(L =mnt2 - ,1 ,2 dicyano 1 ,2 ethylenedithiolate ;L′=phen 5 ,6 dione,1 ,1 0 phenanthroline 5 ,6 dione)的变温磁化率和电子顺磁共振波谱表征结果 .发现微晶粉体型的标题配合物CuLL′具有一定的顺磁性 ,形成四配位的近似于方形的结构 .探讨了这种配合物磁学特性与结构的关系 .更多还原

【Abstract】 The microcrystalline structure and magnetic properties of the complex CuLL′(L=mnt^2-,1,2-dicyano-1,2-dithiolate; L′=phen-5,6-dione,1,10-phenanthroline-5,6-dione)were studied by variable-temperature susceptibility measurements and EPR. The results showed that the complex exist in the forms of microcrystalline particle and high-spin tetracoordinate complex, and possesses remarkable paramagnetism. The experimental EPR observations for the complex are explained by theory.更多还原