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天然和预处理的极大螺旋藻粉对铅的吸附

Adsorption of lead by powdered raw and pretreated biomass(Spirulina maxima)

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【作者】 龚仁敏陈发扬刘必融刘慧君孟菁

【Author】 GONG Ren min 1,2 ,CHEN Fa yang 3,LIU Bi rong 2,LIU Hui jun 2,MENG Jing 3 (1 School of Life Science,Nanjing University,Nanjing 210093,China;2 College of Life Science, 3 College of Environmental Science,Anhui Normal University,Wuhu 241000,China)

【机构】 南京大学生命科学学院安徽师范大学环境科学学院安徽师范大学生命科学学院安徽师范大学环境科学学院 江苏南京210093安徽芜湖241000安徽芜湖241000

【摘要】 采用间歇批次实验的方法研究了极大螺旋藻作为吸附剂去除溶液中铅的可行性 ,以及天然及预处理的藻粉对铅离子的吸附作用和各种操作条件对铅离子吸附的影响。结果表明 ,pH值对吸附的影响较大 ,吸附量随 pH值的增高而增大 ,当 pH值为 5 5时吸附率最高。铅吸附的前 30min为快速吸附阶段 ,6 0min吸附即达平衡状态 ,吸附等温线符合Freundlich方程。单位藻重的铅吸附量随藻生物量的增加而降低 ,预处理生物量的吸附率明显高于天然生物量的吸附率。4种解吸液中 ,0 1mol·L-1的硝酸解吸率最高。

【Abstract】 The feasibility of Spirulina maxima as adsorbent for lead removal from aqueous solution was investigated by interrupted batch mode.The lead adsorption was studied by using raw biomass and pretreated biomass of Spirulina maxima .The effects of operational conditions on lead adsorption were investigated.The adsorption capacities were solution pH dependent.As pH increased,the amount of lead adsorbed increased and the maximum adsorption was obtained at a solution pH of about 5 5.The adsorption rate of lead was very rapid during the initial stages of 30 minutes.The adsorption equilibrium was reached in 60 min.The adsorption isotherm fitted the Freundlich model.The amount of lead adsorbed of per gram biomass decreased with the increase of biomass.The lead removal ratio was even more in pretreated biomass over raw biomass.Among four desorbents studied,0 1 mol·L -1 nitric acid was the most effective lead desorbent.

【关键词】 吸附铅离子预处理极大螺旋藻
【Key words】 adsorptionlead ionpretreatmentSpirulina maxima
【基金】 安徽省教育厅自然科学基金 (2 0 0 3kj15 7);安徽师范大学专项科研基金 (14 3 15 0 0 44 )
  • 【文献出处】 南京农业大学学报 ,Journal of Nanjing Agricultural University , 编辑部邮箱 ,2004年03期
  • 【分类号】X703
  • 【被引频次】15
  • 【下载频次】221
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