【摘要】 研究了Cu CAS CTMAB三元络合物体系,结果表明,其络合物组成为1∶4∶4,λmax=596nm,Δλ=166nm,ε=1.2×105,铜(Ⅱ)的浓度在0.002～1.00μg·ml-1范围内遵守比耳定律,用于超硬材料合成触媒中铜的分析,建立了回归方程,并通过显著性检验,获得了满意的结果。更多还原

【Abstract】 It was found that Cu（Ⅱ） forms a ternary complex with CAS and CTMAB with mole ratio of 1∶4∶4. The absorption maxima of this complex lies at the wavelength of 596nm （Δλ=166nm）, where it has the apparent molar absorptivity of 1.2×10⁵L·mol^-1·cm^-1. Beer′s law holds in the range of 0.1～50μg of Cu（Ⅱ） per 50ml of solution. In its application to the analysis of the catalyst samples, RSD′s obtained were less than 4.5%.更多还原