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银-微量稀土银饰品材料的研究

A Study on Silver-rare Earths Ornamental Materials

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【作者】 王佳夫; 林清华; 石路; 王力军; 王继周;

【Author】 WANG Jia fu 1,LIN Qing hua 1,2 ,SHI Lu 3,WANG Li jun 3,WANG Ji zhou 3 (1. The State Key Laboratory of Rolling Technology and Automation, Northeastern University, Shenyang 110004, Liaoning, China; 2.Materials and Metallurgy Institute, Kunming University of Science and Technology, Kunming 650093, Yunnan, China; 3. Materials and Metallurgy Institute, Northeastern University, Shenyang 110004,Liaoning, China)

【机构】 东北大学轧制技术及连轧自动化国家重点实验室; 东北大学材料与冶金学院; 东北大学材料与冶金学院 辽宁沈阳110004; 辽宁沈阳110004; 昆明理工大学材料与冶金工程学院; 云南昆明650093; 辽宁沈阳110004;

【摘要】 研究了添加微量稀土 (质量分数小于 0 .0 7% )银饰品材料的硬度随变形量及温度的变化规律 ,用扫描电镜观察了材料的显微组织和第二相分布 ,同时对材料的抗硫化性能进行了试验。结果表明 ,添加质量分数为 0 .0 6%左右的微量稀土能够细化晶粒 ,稀土以固溶或球状第二相形式存在 ,可以强化合金 ,有效地延缓了材料的回复与再结晶 ,提高了银饰品材料的抗时效软化能力。其中银钇合金表现了较好的抗硫化物腐蚀的能力

【Abstract】 Some tests on silver ornamental material are carried out by adding rare earths, less than 0.07%,to investigate the dependence of hardness on the temperature and degree of deformation. Microstructure and second phase distribution of the alloys are observed with a scanning electron microscope. A test on sulphidization corrosion resistance of the alloys is carried out. The results show that addition of a trace of rare earth(about 0.06%) can fine the particles of the silver alloys. The rare earths are distributed in the alloys in the form of solid solution or spherical second phase, thus strengthening the alloys, delaying their recovery and recrystallization and improving the age softening resistance of silver ornamental materials. Ag Y alloys have a better ability to resist sulphidization corrosion.

【基金】 原冶金部人教司资助项目 (1 997- 2 0 5)
  • 【文献出处】 矿冶工程 ,Mining and Metallurgical Engineering , 编辑部邮箱 ,2004年01期
  • 【分类号】TG146.3
  • 【被引频次】15
  • 【下载频次】158
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