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低阳离子度交联聚丙烯酸高吸水树脂的性能研究

Study on Performance of Cross - linking Polyacrylic Acid with a Little Cationic Monomer as Superabsorbent Resin

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【作者】 鲁红升黄志宇王健梁媛媛

【Author】 Lu Hongsheng Huang Zhiyu Wang Jian Liang Yuanyuan ( Chemistry and Chemical Engineering College of Southwest Petroleum Institute, Nanchong 637001)

【机构】 西南石油学院化学化工学院西南石油学院化学化工学院 南充 637001南充 637001南充 637001

【摘要】 以AA(丙烯酸)、HMAC(羟丙烯酰胺基已基氯化铵)为原料,NMBA(N,N-亚甲基双丙烯酰胺)为交联剂,通过溶液聚合制得低阳离子度交联聚丙烯酸高吸水性树脂,研究了影响高吸水树脂性能的因素,并考察了其在去离子水中和NaCl、CaCl2、MgCl2溶液中的吸水性,以及高温高压下高吸水树脂的保水性。结果表明,加入HMAC阳离子单体,高吸水树脂的耐盐性增加,初始吸水速率增加,饱和吸水率下降,且高温高压下保水性增强。

【Abstract】 The cross - linking polyacrylic acid with a little cationic monomer as superabsorbent resins were prepared by solution polymerization of AA, HMAC and NMBA, and the factors affecting their performance were investigated. Water - holding performance under high temperature and pressure were investigated. The results showed that earlier absorbency rate and water - holding performance increased, saturation absorbency decreased after HMAC added.

  • 【文献出处】 精细石油化工进展 ,Advances in Fine Fetrochemicals , 编辑部邮箱 ,2004年04期
  • 【分类号】TQ325.14
  • 【被引频次】3
  • 【下载频次】200
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