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桐油改性硼酚醛的耐热性及其复合材料摩擦性能的研究
Heat Resistance of Boron Phenolic Resin Modified by Tung Oil and Frication Property of Its Complex Material
【摘要】 热失重分析表明该桐油、硼双改性酚醛树脂的起始热分解温度≥400℃,450℃时,碳的残留率≥60%,耐热性明显优于普通的酚醛树脂;红外光谱表明了该双改性树脂的碳骨架上引入了桐油分子长碳链,具有一定的柔韧性和油溶性。用该双改性树脂作为基体树脂制备的无石棉编织型制动带,低温摩擦系数达0 50以上,高温摩擦系数可达0 40以上,且摩擦系数恢复性良好。
【Abstract】 Thermogravimetric analysis showed that the initial decomposition temperature of binary-modified phenolic resin by tung oil and boron was above 400 ℃,and remainder mass was above 60% at 450 ℃.IR spectra showed that long chains of molecules of tung oil were bonded on the skeleton of boron phenolic resin.Frication coefficient of non-asbestos woven brake band made with this binary-modified phenolic resin was above 0.50 at low temperature and was above 0.40 at high temperature.The recovery of friction coefficient was well too.
【关键词】 硼酚醛树脂;
改性;
桐油;
摩擦性能;
【Key words】 boron phenolic resin; modifying; tung oil; frication property;
【Key words】 boron phenolic resin; modifying; tung oil; frication property;
【基金】 贵州省工业攻关项目基金资助〔黔科合工字(2000)1067号〕~~
- 【文献出处】 精细化工 ,Fine Chemicals , 编辑部邮箱 ,2004年06期
- 【分类号】TQ323
- 【被引频次】36
- 【下载频次】254