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有机硅/丙烯酸酯共聚物乳液性能的研究
Study on Silicone/Acrylate CopolymericLatex and its Performance
【摘要】 采用反应型乳化剂烷基乙烯基磺酸钠 ( DNS-86)合成了有机硅改性丙烯酸酯共聚乳液 ,考察了乳液的表面张力、稳定性及流变性能。结果表明硅丙乳液的表面张力随有机硅单体用量的增加而减小 ;乳液的冻融稳定性和储存稳定性良好 ,符合涂料的使用要求 ;乳液为非牛顿流体 ,乳液的表观黏度随着有机硅含量的增加而降低。
【Abstract】 The emulsion of vinyl triethoxysilane-acrylate using a polymerizable emulsifier DNS-86 was synthesized. The surface tension, stabilities and rheological properties of silicone-acrylate emulsion were investigated. It was found that the emulsion was a non-Newtonian fluid and had good storage stability and freeze-thaw stability, the surface tension and apparent viscosity of the emulsion decreased with increase of the amounts of organosilicon monomer.
【关键词】 丙烯酸酯;
乙烯基硅氧烷;
乳液聚合;
可聚合型乳化剂;
【Key words】 Acrylate; Vinyl silicone; Emulsion polymerization; Polymerizable emulsifier;
【Key words】 Acrylate; Vinyl silicone; Emulsion polymerization; Polymerizable emulsifier;
- 【文献出处】 胶体与聚合物 ,Chinese Journal of Colloid and Polymer , 编辑部邮箱 ,2004年03期
- 【分类号】TQ630
- 【被引频次】9
- 【下载频次】278