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天然水体中优势菌种非活性细胞吸附Pb2+和Cd2+的热力学及动力学研究

Studies on thermodynamics and kinetics of (Pb2+) and (Cd2+) adsorption onto dominant dead bacteria in natural water

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【作者】 郭平马小凡康春莉李军王羽刘乃喻

【Author】 GUO Ping, MA Xiao-fan, KANG Chun-li, LI Jun, WANG Yu, LIU Nai-yu (Department of Environmental Science, College of Environment and Resources, Jilin University, Changchun 130023, China)

【机构】 吉林大学环境与资源学院环境科学系吉林大学环境与资源学院环境科学系 长春130023长春130023长春130023

【摘要】 研究了长春市伊通河天然水体中优势菌种非活性细胞对Pb2+和Cd2+吸附规律,发现非活性细胞对Pb2+和Cd2+的吸附符合Langmuir和Freundlich热力学方程.非活性细胞吸附Pb2+和Cd2+的动力学过程分为快速阶段和慢速阶段,其中慢速阶段符合二级吸附速率动力学方程.

【Abstract】 The adsorption of (Cd2+) and (Pb2+) onto dominant dead bacteria in natural water was studied. The (results) show that when Langmuir and Freundlich isotherm models were tried to represent the equilibrium data of (Cd2+) and (Pb2+) adsorption onto dominant dead bacteria, equilibrium data fitted very well to both the models in the studied concentration range of (Cd2+) and (Pb2+). The kinetic processes of the adsorption included fast phase and slow phase. Pseudo first-order and pseudo second-order kinetic models were also applied to experimental data on the basis of assuming that the external mass transfer limitations in the system can be neglgected and the adsorption is sorption controlled. The slow phase obeyed the second-order rate expression.

【基金】 吉林省环保局基金(批准号:2001017);吉林大学创新基金(批准号:403010123013).
  • 【文献出处】 吉林大学学报(理学版) ,Journal of Jilin University (Science Edition) , 编辑部邮箱 ,2004年04期
  • 【分类号】X172
  • 【被引频次】16
  • 【下载频次】137
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