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Formation, Isolation and Characterization of a New Ruthenium Complex in Reaction of Acetone Masked Terminal Alkynone with Transfer Hydrogenation Catalyst

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【Author】 GUO, Min-Jiea LI, Daoa SUN, Yan-Huib CHENG, Jiangb ZHANG, Zhao-Guo*,a State Key Laboratory of Organometallics, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China b Department of Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China

【机构】 State Key Laboratory of Organometallics； Shanghai Institute of Organic Chemistry； Chinese Academy of Sciences； Shanghai 200032； China； Department of Chemistry； Nanjing University； Nanjing； Jiangsu 210093； China；

【Abstract】 Reaction of [1S,2S-(Ts-diphen)Ru(II)(p-cymene)] (1S,2S-Ts-diphen=1S,2S-N-tosyl-1,2-diphenylethylenedi- amine) and 2-hydroxy-2-methyl-non-3-yn-5-one under transfer hydrogenation condition gave a ruthenium complex bearing a 2,5-dihydrofuran moiety. The complex was characterized and a possible mechanism for the formation of the complex was proposed.更多还原

【关键词】 ruthenium； transfer hydrogenation； alkyne； alkynone； dihydrofuran；
【Key words】 ruthenium； transfer hydrogenation； alkyne； alkynone； dihydrofuran；

【基金】 Project supported by the National Natural Science Foundation of China (No. 20172067); the Chinese Academy of Sciences; and the Shanghai Mu-nicipal Commission of Science and Technology.

【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2004年12期

【分类号】O621
【下载频次】11

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