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Palladium-Catalyzed Oxidation of Dihydromyrcene to Citronellal in Supercritical Carbon Dioxide

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【Author】 RAN, Xue-Guanga JIANG, Huan-Feng*,a,b ZHU, Xin-Haic a Department of Applied Chemistry, South China University of Technology, Guangzhou, Guangdong 510640, China b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China c Laboratory of Cellulose and Lignocellulosics Chemistry, Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510650, China

【机构】 Department of Applied Chemistry, South China University of Technology Guangzhou, Guangdong 510640, China,Department of Applied Chemistry, South China University of Technology Guangzhou, Guangdong 510640, China； State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China,Laboratory of Cellulose and Lignocellulosics Chemistry, Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510650, China；

【Abstract】 Citronellal was the major product of catalytic oxidation of dihydromyrcene with oxygen using the catalyst comprised of (MeCN)2PdClNO2 and CuCl2 in a tertiary alcohol in supercritical carbon dioxide. It was found that the chemoselectivity of the reaction and the yield of citronellal were greatly affected by the pressure of carbon dioxide, the reaction temperature and the molar ratio of Pd/Cu.更多还原

【关键词】 supercritical carbon dioxide； dihydromyrcene； Pd-catalyzed； oxidation reaction； citronellal；
【Key words】 supercritical carbon dioxide； dihydromyrcene； Pd-catalyzed； oxidation reaction； citronellal；

【基金】 Project supported by the National Natural Science Foundation of China (Nos. 20172053 and 20332030).

【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2004年11期

【分类号】O643.3
【被引频次】1
【下载频次】5

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