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A Novel Debromination of vic-Dibromides to Alkenes with InCl3(cat.)/Sm System in Aqueous Media

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【作者】 王敏王磊李品华晏金灿

【Author】 WANG, Mina WANG, Lei*, a,b LI, Pin-Huaa YAN, Jin-Cana a Department of Chemistry, Huaibei Coal Teachers College, Huaibei, Anhui 235000, China b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

【机构】 Department of Chemistry, Huaibei Coal Teachers College,Department of Chemistry, Huaibei Coal Teachers College,Department of Chemistry, Huaibei Coal Teachers College,Department of Chemistry, Huaibei Coal Teachers College Huaibei, Anhui 235000, China, Huaibei, Anhui 235000, ChinaState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China, Huaibei, Anhui 235000, China, Huaibei, Anhui 235000, China

【Abstract】 A novel debromination of vic-dibromides to alkenes with InCl3(cat.)/Sm system in aqueous media has been de- veloped. The reaction gives the E-isomers with excellent yields.

【基金】 Project supported by the National Natural Science Foundation of China (Nos. 20372024 and 20172018); the Excellent Scientist Foundation of AnhuiProvince (No. 2001040); the Natural Science Foundation of the Education Department of Anhui Province (No. 2
  • 【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2004年08期
  • 【分类号】O621
  • 【下载频次】8
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