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Synthesis, Crystal Structures and Characterization of Ba5LiTiNb9O30

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【作者】 刘韩星邹龙周建方亮张高科欧阳世翕

【Author】 LIU, Han-Xing ZOU, Long ZHOU, Jian) FANG, Liang ZHANG, Gao-Ke OUYANG, Shi-Xi State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Tech-nology, Wuhan, Hubei 430070, China

【机构】 State Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of Tech-nologyWuhanHubei 430070ChinaChina

【Abstract】 A new niobate compound with the chemical composition of Ba5LiTiNb9O30 was synthesized by doping Li+ into the system BaO-TiO2-Nb2O5 in conventional solid state reaction method. The crystalline structure was determined by X-ray diffraction analysis (XRD). The results showed that crystal structure of Ba5LiTiNb9O30 belongs to tetrago-nal tungsten bronze structure with space group P4bm and its unit cell parameters: a=b=1.2512(2) nm, c=0.4008(5) nm. The microstructure of reaction products was observed by scanning electron microscopy (SEM).

【基金】 Project supported by the National Natural Science Foundation of China (Grant No. 20371038); and Ministry of Education of China.
  • 【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2004年05期
  • 【分类号】O614
  • 【下载频次】16
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