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Study on the Radius of an Electrical Spherical Micelle: Functional Theoretical Approach

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【作者】 王正武黄东阳易希璋李干佐

【Author】 WANG, Zheng-Wua,b HUANG, Dong-Yang*,a YI, Xi-Zhangc LI, Gan-Zuob a Medical College, Shantou University, Shantou, Guangdong 515041, China b Key Laboratory of Colloid and Interface Chemistry for State Education Ministry, Shandong University, Jinan, Shandong 250100, China c Institute of Theoretical Chemistry, Shandong University, Jinan, Shandong 250100, China

【机构】 Medical CollegeShantou UniversityInstitute of Theoretical ChemistryShandong UniversityKey Laboratory of Colloid and Interface Chemistry for State Education MinistryShandong University ShantouGuangdong 515041ChinaJinanShandong 250100ChinaShantouJinan

【Abstract】 For the purpose of eliminating restriction, the Poisson-Boltzmann (PB) equation, which represents the potential of the electrical double layer of spherical micelles, can be solved analytically only under the lower potential condi-tion, a kind of iterative method in functional analysis theory has been used. The radius of the spherical particle can be obtained from the diagram of the second iterative solution of the potential versus the distance from the center of the particle. The influences of the concentration of the ions, the charge number of ions, the aggregation number of the particle, the dielectric constant of solvent and the temperature of system on the radius also have been studied.

【基金】 theNationalNaturalScienceFoundationofChina(No.30070178).
  • 【文献出处】 Chinese Journal of Chemistry ,中国化学(英文版) , 编辑部邮箱 ,2004年04期
  • 【分类号】O648
  • 【下载频次】6
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