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光度法测定有机溶剂中微量水
Determination of micro amount of water in organic solvents by spectrophotmetry
【Abstract】 The reaction between 7,7,8,8-tetracyanoquinodimethane(TCNQ)and water in organic solvents was studied.TCNQ and water complex has strong molar absorptivity at 744nm and 840nm.The linear range is 0~7.0%(V/V)or 0~8.0%(V/V)for the determination of water in methanol,ethanol,n-propyl alcohol,2-propanol.The results for ethanol were in agreement with standard results. The recoveries of water in n-propyl alcohol and 2-propanol were 96.6%~101% and 98%~102%,respectively.This is a simple,sensitive and reproducible method for determining water in organic solvents.
【关键词】 水;
7,7,8,8-四氰基对二次甲基苯醌;
分光光度法;
【Key words】 Water; 7; 8; 8-tetracyanoquinodimethane(TCNQ); spectrophotometric;
【Key words】 Water; 7; 8; 8-tetracyanoquinodimethane(TCNQ); spectrophotometric;
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2004年03期
- 【分类号】O657.3
- 【被引频次】2
- 【下载频次】130