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聚四氟乙烯胶乳与碳黑粒子共凝聚行为的研究

Study on Hetero-coagulation of Poly(tetrafluoroethylene) Latex Particles and Carbon Black Particles

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【作者】 朱耕宇陈雪萍陆世浚李胜翁志学

【Author】 Zhu Gengyu Chen Xueping Lu Shijun Li sheng Weng Zhixue(Institute of Polymer Engineering, Zhjiang University, Hangzhou 310027, China;Zhejiang Jusheng Fluorochemical Co. , Ltd, Quzhou 324004,China)

【机构】 浙江大学高分子工程研究所浙江巨圣氟化学有限公司浙江大学高分子工程研究所 浙江杭州 310027浙江杭州 310027浙江衢州 324004浙江杭州 310027

【摘要】 提出了用共凝聚的方法制备填充聚四氟乙烯(PTFE)的思想,以Al(NO3)3、CaCl2、Kcl为凝聚剂进行PTFE分散乳液与碳黑粒子的共凝聚。考察了胶乳种类、凝聚温度、搅拌转速等对共凝聚过程的影响规律,初步探讨了共凝聚粒子的成粒机理。结果表明共凝聚粒子是疏水性的,粒子内碳黑分散均匀。

【Abstract】 The idea of preparing filled poly(tretrafluorothyleneXPTFF) with hetero-coagulation method was introduced. Hetero-coagulation of PTFE latex particles and carbon black particles was studied with coagulation agents Al(NO3)3, CaCl2 and KCl. The influence of latex type, temperature and agitation speed on hetero-coagulation process were investigated. The mechanism of forming composite particles was discussed. The composite particles prepared by this means were hydropho-bic. The carbon black particles were dispersed in hetero-coagulated particles equably.

  • 【文献出处】 化学反应工程与工艺 ,Chemical Reaction Engineering and Technology , 编辑部邮箱 ,2004年02期
  • 【分类号】TQ316.6
  • 【被引频次】5
  • 【下载频次】206
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